Fly Ash (Class F) MSDS

Fly Ash (Class F) MSDS

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

SUPPLIER NAME : M/s. MAXWORTH MINRALS TRADING PVT. LTD.,

ADDRESS : D No. 48-14-116/6,
4TH FLOOR, LAKSHMI ROYAL PLAZA,
RESAPUVANIPALEM,
VISKAHAPATNAM: 530003, AP, INDIA

Telephone Number : (91) 891 256 6263
E-MAIL : enquiry@maxworthgroup.com.au
Web : www.maxworthgroup.com.au

MSDS DATE: 05.01.2018

SYNONYMS : FGA, FINE GRADE ASH, FLY ASH
USES : ASPHALT ADDITIVE, CEMENT ADDITIVE, CONCRETE ADDITIVE, CONSTRUCTION FILLER, INDUSTRIAL APPLICATIONS, RAW MATERIAL, SOIL STABILIZATION.

2. HAZARDOUS IDENTIFICATION : CLASSIFIED AS NON HAZARDOUS ACCORDING TO ASCC CRITERIA

RISK PHRASES :

R20 : HARMFUL BY INHALATION.
R36/37/38 : IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN
R40 : LIMITED EVIDENCE OF CARCINOGENIC EFFECT
R48/20 : HARMFUL DANGER OF SERIOUS DAMAGE TO HEALTH BY PROLONGED THROUGH INHALATION.

SAFETY PHRASES :

S22 : DO NOT BREATH DUST
S24/25 : AVOID CONTACT WITH SKIN AND EYES
S36/37/39 : WEAR SUIATBLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
S38 : IN CASE OF INSUFFICIENT VENTILLATION, EAR SUIATBLE RESPIRATORY EQUIPMENT
S51 : USE ONLY IN WELL VENTILATED AREAS

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

UN NO. : NONE ALLOCATED
PACKING GROUP : NONE ALLOCATED
DG CLASS : NONE ALLOCATED
HAZCHEM CODE : NONE ALLOCATED
SUBSIDIARY RISKS(S) : NONE ALLOCATED
EPG : NONE ALLOCATED

3. COMPOSITION / INFORMATION ON INGREDIENTS :
Ingredient Formula CAS No. Content
QUARTZ (SILICA CRYSTALLINE) Si-O2 14808-60-7 60-70%
CALCIUM OXIDE Ca-O 1305-78-8 <12%
IRON OXIDE Fe2-O3 1309-37-1 <4%
ALUMINIUM OXIDE AL2-O3 1344-28-1 10-20%
MAGNESIUM OXIDE MG-0 1309-48-4 <1%

4. FIRST AID MEASURES :
Eye

If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a poisons information centre, a doctor, or for at least 15 minutes.

Inhalation

If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.

Skin

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a poisons information centre or a doctor.

Ingestion

For advice, contact a poisons information centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed, do not induce vomiting.

Advice to Doctor

Treat symptomatically

5. FIREFIGHTING MEASURES :
Flammability

Non Flammable. May evolve toxic gases if strongly heated.

Fire and explosion

No fire or explosion hazard exists.

Extinguishing

Prevent contamination of drains or waterways.

Hazchem code

None allocated

6. ACCIDENTAL RELEASE MEASURES :
Spillage

Contact emergency services if required. Use personal protective equipment. Clear areas of all unprotected personnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Avoid generating dust.

7. STORAGE AND HANDLING :
Storage

Store tightly sealed in a cool, dry, well ventilated area, removed from acids, alkalis, heat or ignition sources and food stuffs. Ensure containers are adequately labeled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.

Handling

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION :
Exposure Stds Ingredient Reference TWA STEL
ppm Mg
M3
ppm Mg
M3
Silica, Crystalline Quartz ASCC (AUS) 0.1
Biological limits No biological limit allocated
Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation is recommended. Maintain dust levels below the recommended exposure standard.
PPE Wear dust-proof goggles and rubber or PVC gloves. When using large quantities or where heavy contamination is likely, wear: coveralls. At high dust levels, wear: a Full-face class P3 (Particulate) or an Air-line respirator. Where an inhalation risk exists, wear: a class P1 (Particulate) respirator.

9. PHYSICAL & CHEMICAL PROPERTIES
Appearance GRAY POWDER Solubility (water) < 50 g/L
Odour ODOURLESS Specific Gravity 2.15 to 2.25
Ph 3 to 4 % Volatiles < 2%
Vapour Pressure Not available Flammability Non Flammable
Vapour Density Not available Flash point Not relevant
Boiling Point Not available Upper explosion limit Not relevant
Melting Point >1600 oC Lower explosion limit Not relevant
Evaporation Rate Not available
Bulk density 800-1000 Kg/m3

10. STABILITY & REACTIVITY
Chemical stability Stable under recommended conditions of storage
Conditions to avoid Avoid contact with incompatible substances.
Material to avoid Incompatible with acids (e.g. nitric acid) and alkalis (e.g. hydroxides)
Decomposition May evolve toxic gases if heated to decomposition.
Hazardous reactions Polymerization is not expected to occur.

11. TOXICOLOGICAL INFORMATION
Health hazard summary Irritant. Use safe work practices to avoid eye or skin contact and inhalation. Chronic exposure to crystalline silica may result in lung fibrosis (silicosis). However, due to the low levels of crystalline silica, chronic health effects are not anticipated with normal use. Crystalline silica is classified as carcinogenic to humans (IARC Group 1)
Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns with prolonged contact.
Inhalation High Chronic toxicity – irritant. Over exposure to dust may result in mucous membrane irritation of the respiratory tract. Chronic exposure to crystalline silica may result in silicosis (lung fibrosis). Crystalline silica is classified as carcinogenic to humans (IARC Group 1).
Skin Irritant. Contact may result in irritation, redness, pain and rash. May cause sensitization by skin contact
Ingestion Low to moderate toxicity. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain and diarrhoea.
Toxicity data Quartz (Silica Crystalline) (14808-60-7)
LCLo (Inhalation) : 300 ug/m3/10 years (human)
LDLo (Intravenous) : 200 mg/kg (rat)
LDLo (Intravenous) : 20 mg/kg (dog)
TCLo (Inhalation) : 16 000 000 particles / ft3/8 hours/17.9 years (human-fibrosis)

12. ECOLOGICAL INFORMATION
Environment The main component/s of this product are not anticipated to cause any adverse effects to plants or animals.

13. DISPOSAL CONSIDERATION
Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose to approved council landfill. Contact the manufacturer if additional information is required.
Legislation Dispose of in accordance with relevant local legislation

14. TRANSPORT INFORAMATION
NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE
Shipping Name : None allocated
UN No. None allocated DG Class : None allocated Subsidiary Risk(s): None allocated
Packing group : None allocated Hazchem group : None allocated EPG : None allocated

15. REGULATORY INFORMATIONS
Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the standard for the uniform scheduling of drugs and poisons (SUSDP)
AICS All chemicals listed on the Australian Inventory of Chemical substances (AICS)

16. OTHER INFORMATION
Additional Information Crystalline silica is present in Fly Ash as an impurity. The amount depends on the crystalline silica content of the source coal.
ALUMINO SILICATES: When alumina silicates have been exposed to service temperatures exceeding 982o C for prolonged periods, cristobalite, a form of crystalline silica may be formed. Exposure to cristobalite dust may cause pulmonary fibrosis-silicosis. A hazard is only anticipated during demolition of used refractory materials. Cristobalite is classified as carcinogenic to humans (IARC Group 1).
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air supplied respirators should be considered where prolonged or repeated use is necessary.
ABBREVIATIONS:
ADB – Air Dry basis
BEI-Biological exposure indices(s)
CAS# – Chemical abstract service number-used to uniquely indentify chemical compounds
CNS – Central Nervous System
EINECS – European inventory of existing commercial chemical substances
IARCS – International agency for research on cancer
M – moles per ltr, a unit of concentration.
Mg/m3 – Milligrams per cubic mtr
NOS – Not otherwise specified
NTP – National toxicology program
OSHA – Occupational safety fir health administration
pH – relates to hydrogen ion concentration using a scale of 0(high acidic) to 14 (highly alkaline)
ppm – Parts per million
RTECS – registry of toxic effects of chemical substances
TWA/ES -Time weighted average or exposure standard.
HEALTH EFFECTS FROM EXPOSURE : It should be noted that the effects from exposure to this product will depend on several factors including: frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a Chem Alert report which would encompass all possible scenarious, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES : The recommendation for protective equipment contained within this Chem Alert is provided as a guide only. Factors such as methods of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.
Report Status: This document has been compiled by RMT on behalf of the manufacturer of the product and serves as the manufacturers safety data sheet (‘SDS’).
It is based on information concerning the product which has been provided to RMT by the manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury, or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.
Prepared by M/S. MAXWORTH MINERALS TRADING PVT. LTD.,
D No 48-14-116/6, LAKSHIMI ROYAL PLAZA,
FOURTH FLOOR, RESAPUVANIPALEM,
VISAKHAPATNAM – 530003, INDIA
TEL : (91) 891 256 6263

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